Samsung Kies is a program for transfering files between your Samsung mobile device and computer, syncronizing your Outlook contacts and tasks and much more.
If any file can not be deleted, then you can use the program LockHunter, which removes the active connections of other applications to that file, which allow you to change or delete file.
Nice little program that enables you to close all your opened applications and windows with one single click. It works in Windows XP and Windows 7 and doesn't need installing.
Pixlr is a free and probably the best web based image editor. I will show you how to open and and resize an image, I'm sure you will be impressed how well the web app actually works.
If you want to put your video files online using HTML5 then it's recommended to have three different formats for a full browser support. Those formats are mp4, ogv and webm.
VMware player is a great free tool for creating virtual machines and desktops. For instance, you can create a new virtual computer to install and test the new Windows 8 Consumer Preview.
Power Search was a real useful feature and there is now good reason why Apple decided to ditch/hide in iTunes version 11. But luckily you can bring it back quite easily. Check it out.