In this day of age, it's very practical to have a Windows 7 installation on your USB key, for many netbooks and devices don't come with CD/DVD drives anymore.
Explorer in Windows 8 is quite updated and it is as much as possible adapted to the user. They have also added the option to quickly access the Command Prompt terminal window.
If you are using removable disk or USB key then you should look at this lesson. I will show you how you can safely remove your device from computer without the fear of losing data.
If you leave your computer running on a 24/7 basis you might be interested in determining the amount of uptime that has accumulated since the last reboot.
If you can't copy files that are bigger than 2 or 4 GB, usually HD movies and such, on to your USB key, it's usually due to the file system the USB key is formatted to.