Some installations or settings changes require you to restart your computer. In most cases you don't need to actually reboot it, you only need to restart the explorer.exe process.
In Google Chrome you can set the pages you want them to open on a startup. The option is a bit hidden that's why a lot of people are having hard time when trying to find it.
Really great and free service where you can chat using a bunch of services like Skype or Google Talk within your web browser, meaning you don't need to install anything on your computer.
If you put your computer into hibernation, the next time you turn it on, you'll get all your windows and programs open just the way they were before the shutdown.