You are trying to install or open an app that didn't come from the Mac App Store but you got a message saying App can't be opened because it is from an unidentified developer. This is how you bypass it.
You deleted everything from your USB key or a drive, so there should be enough free space to copy the new files, but you still get the not enough free space message in Mac OS X? This is what you need to do.
Mac OS X Moutain Lion and its Safari web browser sharing options allow you to share and send any web page vie email as a PDF attachment in a matter of two clicks.
You can add multiple desktops to the Mac OS X Mountain Lion by using Mission Control, formerly known as Spaces. Can be really useful if you are a busy multi-tasker.
If you are more of a visual person and would like to organize your folders and files using different colors, than check it out how to use color labels in Mac OS X.
VirtualBox is a great free cross-platform virtualization program that enables you to run Windows, Linux, Mac OS X and other operating systems on you Windows, OS X or Linux computer.
If you experience an Mac OS X program to freeze and you cannot exit it by clicking quit or using a keyboard shortcut, you can always force it to quit using the Activity Monitor.