VMware player is a great free tool for creating virtual machines and desktops. For instance, you can create a new virtual computer to install and test the new Windows 8 Consumer Preview.
Nice little program that enables you to close all your opened applications and windows with one single click. It works in Windows XP and Windows 7 and doesn't need installing.
If you are a heavy twitter use, possibly with more then one account, than I suggest you to give Tweetdeck a try. You can arrange, schedule, monitor and manage your tweets with ease.
Pixlr is a free and probably the best web based image editor. I will show you how to open and and resize an image, I'm sure you will be impressed how well the web app actually works.
Samsung Kies is a program for transfering files between your Samsung mobile device and computer, syncronizing your Outlook contacts and tasks and much more.