Nice little program that enables you to close all your opened applications and windows with one single click. It works in Windows XP and Windows 7 and doesn't need installing.
Pixlr is a free and probably the best web based image editor. I will show you how to open and and resize an image, I'm sure you will be impressed how well the web app actually works.
VMware player is a great free tool for creating virtual machines and desktops. For instance, you can create a new virtual computer to install and test the new Windows 8 Consumer Preview.
Power Search was a real useful feature and there is now good reason why Apple decided to ditch/hide in iTunes version 11. But luckily you can bring it back quite easily. Check it out.